1,1,2,2-tetrakis(4-bromophenyl)ethylene

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CAS: 61326-44-1
MF: C26H16Br4
MW: 648.02124
Synonyms: 1,1,2,2-tetrakis(4-bromophenyl)ethylene

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Jin-Gui Qin

Wuhan University
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Zhen LI

Wuhan University
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Jianyong Zhang

Sun Yat-Sen University
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Zhenguo Chi

Sun Yat-sen University
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Xiang Ma

East China University of Science and Technology
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Ziqiang Lei

Northwest Normal University
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HengChang Ma

Northwest Normal University
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Mircea Dinca

Massachusetts Institute of Technology
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Hong-Cai Zhou

Texas A&M University
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F. Christopher Pigge

University of Iowa
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Co-reporter: Pradeep P. Kapadia, John C. Widen, Mackenzie A. Magnus, Dale C. Swenson, F. Christopher Pigge
pp: 2519-2522
Publication Date(Web):11 May 2011
DOI: 10.1016/j.tetlet.2011.03.029
Two tetrapyridyl-substituted tetraphenylethylenes have been prepared via Suzuki coupling between tetrabromo tetraphenylethylene and 3- or 4-pyridine boronic acid. Both compounds exhibit aggregation-induced emission as determined by solid state fluorescence spectroscopy and solution phase fluorescence measurements performed in aqueous/organic solvent mixtures. Solution phase fluorescence was also found to be switchable as a function of pH. 3-Pyridyl-substituted tetraphenylethylene has been structurally characterized by X-ray crystallography.Image for unlabelled figure