178879-60-2|Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium (II) Rh2(R- DOSP)4

Collect

BASIC PARAMETERS Find an error

CAS: 178879-60-2

MF: 4[C23H37NO4S].2[Rh]

MW: 1900.24872

Synonyms: Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium (II) Rh2(R- DOSP)4

Supply Source

I can Supply this

REPORT BY

Huw M. L. Davies

Emory University

follow

Guide to enantioselective dirhodium(II)-catalyzed cyclopropanation with aryldiazoacetates

Co-reporter: Kathryn M. Chepiga, Changming Qin, Joshua S. Alford, Spandan Chennamadhavuni, Timothy M. Gregg, Jeremy P. Olson, Huw M.L. Davies

pp: 5765-5771

Publication Date(Web):

DOI: 10.1016/j.tet.2013.04.075

Pauline Chiu

The University of Hong Kong

follow

Desymmetrization of meso [3.2.1]oxabicyclic systems using metal-catalysed asymmetric intramolecular C–H insertion

Co-reporter: Xiaomei Zhang, Zhengning Li, John C.K. Chu, Pauline Chiu

pp: 6763-6766

Publication Date(Web):14 December 2011

DOI: 10.1016/j.tetlet.2011.10.026

Diazoketone derivatives of meso 8-oxabicyclo[3.2.1]octen-3-ones were desymmetrized by an intramolecular C–H insertion mediated by chiral copper and dirhodium catalysts to generate oxatricyclic systems with up to 5 contiguous stereogenic centres and 50% ee. Image for unlabelled figure