6,8-Methanoisoquinolin-3(2H)-one, 5,6,7,8-tetrahydro-7,7-dimethyl-,(6R,8R)-

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CAS: 330809-01-3
MF: C12H15NO
MW:
Synonyms: 6,8-Methanoisoquinolin-3(2H)-one, 5,6,7,8-tetrahydro-7,7-dimethyl-,(6R,8R)-

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Hoi-Lun Kwong

City University of Hong Kong
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Co-reporter: Chui-Shan Tsang, Chi-Chung Yee, Shek-Man Yiu, Wing-Tak Wong, Hoi-Lun Kwong
pp: 167-177
Publication Date(Web):24 November 2014
DOI: 10.1016/j.poly.2014.05.062
With a series of chiral pyridine-based tetradentate pyridyl-thiazole ligands L, three types of binuclear helical metal complexes were synthesized. They were the Re(I) single-stranded complexes of formula [Re2(L)(CO)6Br2], the Ag(I) double-stranded complexes of formula [Ag2(L)2](ClO4)2 and the Cu(II) triple-stranded complex of formula [Cu2(L)3](ClO4)4. Each type of them has been characterized using CD spectroscopy and if possible 1H NMR spectroscopy. Three single crystal structures, one from each type, have been determined.Graphical abstractWith a series of chiral pyridine-based tetradentate pyridyl-thiazole ligands L, three types of binuclear helical metal complexes were synthesized. The structures of these helicates were characterized with CD spectroscopy and X-ray crystallography.Image for unlabelled figure