Silane, trichloro(heptadecafluorooctyl)-

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CAS: 220791-24-2
MF: C8F17SiCl3
MW: 553.5029
Synonyms: Silane, trichloro(heptadecafluorooctyl)-

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Ching-Ping Wong

Georgia Institute of Technology
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Co-reporter: Yan Liu, Ziyin Lin, Wei Lin, Kyoung Sik Moon, and C. P. Wong
pp: 3959
Publication Date(Web):July 5, 2012
DOI: 10.1021/am300778d
Tuning the surface wettability is of great interest for both scientific research and practical applications. We demonstrated reversible transition between superhydrophobicity and superhydrophilicity on a ZnO nanorod/epoxy composite film. The epoxy resin serves as an adhesion and stress relief layer. The ZnO nanorods were exposed after oxygen reactive ion etching of the epoxy matrix. A subsequent chemcial treatment with fluoroalkyl and alkyl silanes resulted in a superhydrophobic surface with a water contact angle up to 158.4° and a hysteresis as low as 1.3°. Under UV irradiation, the water contact angle decreased gradually, and the surface eventually became superhydrophilic because of UV induced decomposition of alkyl silanes and hydroxyl absorption on ZnO surfaces. A reversible transition of surface wettability was realized by alternation of UV illumination and surface treatment. Such ZnO nanocomposite surface also showed improved mechanical robustness.Keywords: reversible wettability; UV irradiation; ZnO nanocomposite films;

Rebecca Cademartiri

Iowa State University
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David A. Schiraldi

Case Western Reserve University
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Wei Wu

Nanjing University
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Markus Klapper

Max-Planck-Institute for Polymer Research
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Hans-Juergen Butt

Max Planck Institute for Polymer Research
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TianBo Zhao

Beijing Institute of Technology
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