By the combination of divergent and convergent approach, a new series of NLO dendrimers (G1-PFPh-NS-GL to G3-PFPh-NS-GL) was conveniently prepared with satisfied yields through the powerful “click chemistry” reaction, in which perfluoroaromatic rings were introduced in the periphery, two types of chromophores were arranged with regular AB structure, and their topological structure was improved to a more spherical shape. All the dendrimers demonstrated good processability, and G1-PFPh-NS-GL exhibited the highest NLO effect of 221 pm/V among the three dendrimers.Keywords: dendrimers; isolation chromophore; nonlinear optical (NLO) materials; the Ar/ArF self-assembly effect; “star-type” chromophore;

The power of ion mobility spectrometry–mass spectrometry (IMS-MS) as an analytical technology for differentiating macromolecular architecture is demonstrated. The presence of architectural dispersity within a sample is probed by sequentially measuring both the drift time and the mass-to-charge ratio for every component within a polymer sample. The utility of this technology is demonstrated by investigating three poly(ethylene glycol) (PEG) architectures with closely related average molecular weights of about 9000 Da: a linear PEG, an unevenly branched miktoarm star PEG, and evenly branched homoarm star PEGs. The three architectures were readily distinguished when analyzed separately as “pure” architectures or when analyzed as mixtures. IMS-MS results are contrasted with matrix-assisted laser desorption/ionization-MS and viscometry measurements.