Co-reporter:Xue-Song Zang, Hua-Qiao Tan, Qiong Wu, Yan Li, Yang-Guang Li, En-Bo Wang
Inorganic Chemistry Communications 2010 Volume 13(Issue 4) pp:471-474
Publication Date(Web):April 2010
DOI:10.1016/j.inoche.2010.01.011
A new butterfly-like compound K5Na2[Mo9V3O38]·9H2O 1 has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, TG analysis, UV–vis spectroscopy, X-ray photoelectron spectroscopy (XPS), cyclic voltammogram and single-crystal X-ray diffraction analysis. Compound 1 is a new butterfly-like molybdodivanadate composed by Mo (VI) and V (V) with the Mo/V ratio 3:1, the polyoxoanion [Mo9V3O38 ]7− can be described as two {MMo4O18} (M = Mo/V) units connected by one {V2O8} core. The photocatalyst property of compound 1 has been investigated, which shows a good photocatalyst for degradation of RhB.A new butterfly-like compound K5Na2[Mo9V3O38]·9H2O, which is composed of Mo(VI) and V(V) with the Mo/V ratio 3:1, has been obtained. The polyoxoanion [Mo9V3O38 ]7− can be described as two {MMo4O18} (M = Mo/V) units connected by one {V2O8} core. The {MMo4O18} units seem as two “wings”, while the {V2O8} core is like the “trunk” of the butterfly. Thus they composed the novel butterfly-like polyoxoanion.
Co-reporter:Yan Li, Yang-Guang Li, Zhi-Ming Zhang, Qiong Wu, En-Bo Wang
Inorganic Chemistry Communications 2009 Volume 12(Issue 9) pp:864-867
Publication Date(Web):September 2009
DOI:10.1016/j.inoche.2009.06.033
We report the {W72V30} composed of 12 pentagonal {(W)W5} units and 30 [VO(H2O)]2+ linkers. This compound was characterized by the elemental analysis, thermogravimetry, X-ray diffraction analysis, spectroscopic methods (IR, UV/Vis, Raman), XPS, EPR, magnetic measurements and BVS calculations. This is the second member in the pentagonal {(W)W5}-based polyoxotungstate family.A new {W72V30} spherical cage composed of 12 pentagonal {(W)W5} moieties and 30 [VO(H2O)]2+ linkers was obtained, representing the second member in the pentagonal {(W)W5}-based polyoxotungstate family.
![Tungstate(3-),tetracosa-m-oxododecaoxo[m12-[phosphato(3-)-kO:kO:kO:kO':kO':kO':kO'':kO'':kO'':kO''':kO''':kO''']]dodeca-, sodium (1:3)](http://img.cochemist.com/ccimg/12100/12026-98-1.png)
![Tungstate(3-),tetracosa-m-oxododecaoxo[m12-[phosphato(3-)-kO:kO:kO:kO':kO':kO':kO'':kO'':kO'':kO''':kO''':kO''']]dodeca-, sodium (1:3)](http://img.cochemist.com/ccimg/12100/12026-98-1_b.png)
![1H-1,2,4-Triazole, 1,1'-[[1,1'-biphenyl]-4,4'-diylbis(methylene)]bis-](/data/chemimg/102600/960041-69-4.png)
![1H-1,2,4-Triazole, 1,1'-[[1,1'-biphenyl]-4,4'-diylbis(methylene)]bis-](/data/chemimg/102600/960041-69-4_b.png)
![Tungstate(10-), [m9-[orthosilicato(4-)-kO:kO:kO:kO':kO':kO'':kO'':kO''':kO''']]pentadeca-m-oxopentadecaoxonona-, sodium (1:10)](http://img.cochemist.com/ccimg/64700/64684-57-7.png)
![Tungstate(10-), [m9-[orthosilicato(4-)-kO:kO:kO:kO':kO':kO'':kO'':kO''':kO''']]pentadeca-m-oxopentadecaoxonona-, sodium (1:10)](http://img.cochemist.com/ccimg/64700/64684-57-7_b.png)
![Tungstate(3-),tetracosa-m-oxododecaoxo[m12-[phosphato(3-)-kO:kO:kO:kO':kO':kO':kO'':kO'':kO'':kO''':kO''':kO''']]dodeca-,hydrogen (1:3)](http://img.cochemist.com/ccimg/1400/1343-93-7.png)
![Tungstate(3-),tetracosa-m-oxododecaoxo[m12-[phosphato(3-)-kO:kO:kO:kO':kO':kO':kO'':kO'':kO'':kO''':kO''':kO''']]dodeca-,hydrogen (1:3)](http://img.cochemist.com/ccimg/1400/1343-93-7_b.png)