M. Kawasaki

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Organization: Tohoku University , Japan
Department: Institute for Material Research
Title: (PhD)
Co-reporter:Masaki Nakano;Atsushi Tsukazaki;Akira Ohtomo;Kazunori Ueno;Shunsuke Akasaka;Hiroyuki Yuji;Ken Nakahara;Tomoteru Fukumura;Masashi Kawasaki
Advanced Materials 2010 Volume 22( Issue 8) pp:876-879
Publication Date(Web):
DOI:10.1002/adma.200902162
Co-reporter:Masaki Watanabe, Takuji Kita, Tomoteru Fukumura, Akira Ohtomo, Kazunori Ueno and Masashi Kawasaki
ACS Combinatorial Science 2008 Volume 10(Issue 2) pp:175
Publication Date(Web):February 16, 2008
DOI:10.1021/cc700094a
A high-throughput method has been developed to evaluate the Seebeck coefficient and electrical resistivity of combinatorial thin-film libraries of thermoelectric materials from room temperature to 673 K. Thin-film samples several millimeters in size were deposited on an integrated Al2O3 substrate with embedded lead wires and local heaters for measurement of the thermopower under a controlled temperature gradient. An infrared camera was used for real-time observation of the temperature difference ΔT between two electrical contacts on the sample to obtain the Seebeck coefficient. The Seebeck coefficient and electrical resistivity of constantan thin films were shown to be almost identical to standard data for bulk constantan. High-throughput screening was demonstrated for a thermoelectric Mg−Si−Ge combinatorial library.
Co-reporter:A. Tsukazaki;Y. Ohno;T. Kita;A. Ohtomo;H. Ohno
Science 2007 Volume 315(Issue 5817) pp:1388-1391
Publication Date(Web):09 Mar 2007
DOI:10.1126/science.1137430

Abstract

We observed Shubnikov–de Haas oscillation and the quantum Hall effect in a high-mobility two-dimensional electron gas in polar ZnO/MgxZn1–xO heterostructures grown by laser molecular beam epitaxy. The electron density could be controlled in a range of 0.7 × 1012 to 3.7 × 1012 per square centimeter by tuning the magnesium content in the barriers and the growth polarity. From the temperature dependence of the oscillation amplitude, the effective mass of the two-dimensional electrons was derived as 0.32 ± 0.03 times the free electron mass. Demonstration of the quantum Hall effect in an oxide heterostructure presents the possibility of combining quantum Hall physics with the versatile functionality of metal oxides in complex heterostructures.

Co-reporter:M. Ohtani;H. Kishida;K. Hirota;H. Sakurada;N. Kawamoto;Y. Murakami;K. Ueno;Y. Okimoto;J. Matsuno;T. Makino;Y. Segawa;Y. Tokura;H. Okamoto;D. Shindo
Advanced Materials 2006 Volume 18(Issue 19) pp:2541-2544
Publication Date(Web):14 SEP 2006
DOI:10.1002/adma.200501759

Sr2TMO3 (TM = Ni,Co) compounds with 1D TM-O chains have been successfully synthesized in the form of single-crystalline thin films using a combinatorial approach. The crystal structure is examined using X-ray diffraction and high-resolution TEM (see figure). Polarized absorption spectroscopy and third-harmonic generation spectroscopy reveal a 1D electronic structure and sizable nonlinear optical susceptibility, respectively, for Sr2NiO3.