Polymer electrolytes containing N,N′-(trans-cyclohexane-1,4-diyl)dibenzamide linkages, polyethylene ((CH₂)_m, m = 2, 4, 10) spacers, and bis(trifluoromethanesulfonyl)amide (TFSA) or bis(fluorosulfonyl)amide (FSA) counteranions (polymer abbreviation: CDBAm•X; m = 2, 4, 10; X = TFSA, FSA) have been synthesized, adding to our previous report (m = 6). In addition, their ability to effect the gelation of six ionic liquids and the properties of the resulting ionogels have been examined. The polymers, except for CDBA10•TFSA, effect the gelation for all ionic liquids used in this study at fairly low concentrations (0.9–50 g/L). Ionogel ionic conductivity is not dependent on the spacer length, but does decrease slightly as increasing amounts of the gelatinizer are introduced. In contrast to ionic conductivity, the temperatures at which these ionogels transition into isotropic fluids is dependent on the spacer length; the gel composed of [EMI][FSA] and 100 g/L of CDBA6•FSA transforms at 120 °C, while the gel composed of [EMI][FSA] and 5 g/L of CDBA2•FSA does not transform into a sol even when temperatures become 155 °C. In brief, ionogel heat resistance can be improved by changing the spacer length of the polyelectrolyte. Finally, it has been determined using cyclic voltammetry that the potential window of the polyelectrolytes is particularly wide, ranging from −1.6 to 2.5 V. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 249–255

In this article, novel gel-forming materials based on oligomeric and polymeric electrolytes for not only water but also organic solvents, including ionic liquids, are highlighted especially the synthesis, derivatization, and physical property. The oligoelectrolytes with cationic pyridinium backbone can be very easily prepared by the intermolecular quaternization of the ampholytic monomer. The ionene polymers with N,N′-(p-phenylene)dibenzamide linkages as polyelectrolyte were also straightforwardly synthesized in high yields by the copolymerization of 1,4-bis[4-(chloromethyl)benzamide]benzene and commercially available α,ω-ditertiary amines. The oligo- and polyelectrolytes provided physical hydrogels under ca. 1–5 wt% of the concentrations after heating and cooling at room temperature without any other additives. These cationic gelators have characteristic properties, such as acid resistance, a self-healing nature after mechanical collapse, and a dispersant ability for single-walled carbon nanotubes, which have been rarely attainable for conventional physical gelators. © 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Chem Rec 10: 230–242; 2010: Published online in Wiley InterScience (www.interscience.wiley.com) DOI 10.1002/tcr.201000007