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Xin Xu

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Name: 徐信; Xu, Xin
Organization: Soochow University , China
Department:
Title: Professor(PhD)
Frustrated Lewis pair behavior of a neutral scandium complex
Co-reporter:Kejian Chang
Dalton Transactions 2017 vol. 46(Issue 14) pp:4514-4517
Publication Date(Web):2017/04/05
DOI:10.1039/C7DT00676D
An easily-accessible neutral scandium complex Sc[OC(CH3)2CH2PPh2][O-2,6-tBu2-C6H3]2[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.
Frustrated Lewis pair behavior of a neutral scandium complex
Co-reporter:Kejian Chang and Xin Xu
Dalton Transactions 2017 - vol. 46(Issue 14) pp:NaN4517-4517
Publication Date(Web):2017/03/09
DOI:10.1039/C7DT00676D
An easily-accessible neutral scandium complex Sc[OC(CH3)2CH2PPh2][O-2,6-tBu2-C6H3]2[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.
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