We report a novel method to prepare soft colloids with well-controlled softness. The softness of the colloids was characterised by atomic force microscopy and rheometry. Possible applications of such soft colloids in uniform particle coatings are demonstrated.

This article describes a facile and promising method to prepare uniform, non-spherical colloidal particles with shape and chemical anisotropies. We first synthesize polystyrene (PS) colloids with a concave multi-dimple structure, through a unique combination of two-stage dispersion polymerizations and a programmed feeding of cross-linker during the synthesis. These concave particles, after a seeded polymerization process, can be swelled out to precisely controlled shapes by varying the amounts of the swelling chemicals. A myriad of concave- and convex-shaped colloidal particles, including hemispheres, peanuts and bowls are obtained. In addition, we explore the potential applications of the synthesized anisotropic colloids by looking at the field-driven directional self-assembly, the optical hiding effect and their use as colloidal surfactants.

Colloidal particles in a water–lutidine (WL) binary liquid mixture experience temperature-dependent attraction close to the mixture’s demixing temperature. This temperature-tunable interaction can be potentially harnessed to assemble colloids and grow colloidal crystals. In this article, for the first time a novel attractive force gradient method is presented to fabricate high-quality, single-domain colloidal crystals. The well-controlled attractive force gradient here arises from a temperature gradient in the WL mixture. The nucleation of colloidal crystals in such a WL mixture preferably occurs in the high-temperature region because of the stronger attraction there. Crystallization propagates from the high-temperature region to the low-temperature region in a well-controlled way. The growth of the colloidal crystal is characterized in detail by Voronoi construction, the pair correlation function, and the orientational order parameter. It is found that the number of crystal-like particles increases with time, and a single-domain 2D colloidal crystal can be produced. The mechanism of the defect-free crystallization process is discussed on the basis of an analogy to cluster beam deposition methods. This study demonstrates an efficient and robust way to prepare colloidal crystals with little to no defects, being suitable for applications such as colloidal lithography and the fabrication of perfect 3D colloidal crystals.

We report a novel method to prepare soft colloids with well-controlled softness. The softness of the colloids was characterised by atomic force microscopy and rheometry. Possible applications of such soft colloids in uniform particle coatings are demonstrated.