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Zhen Fang

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Organization: University of North Carolina at Chapel Hill
Department: Department of Chemistry
Title:
Triphenylamine derivatized phenylacetylene macrocycle with large two-photon absorption cross-section
Co-reporter:Zhen Fang, Marek Samoc, Richard D. Webster, Anna Samoc, Yee-Hing Lai
Tetrahedron Letters 2012 Volume 53(Issue 36) pp:4885-4888
Publication Date(Web):5 September 2012
DOI:10.1016/j.tetlet.2012.07.003
A phenylacetylene macrocycle (PAM) derivative containing triphenylamine as the framework was synthesized in one-step Sonogashira coupling. The photophysical and electrochemical properties were investigated in details. This hexamer shows significant enhancement in two-photon absorption cross-section relative to reported PAM derivatives.
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